Using the IIS admin MMC, you should be able to change it in:<br><br>Default SMTP Virtual Server Properties -> Delivery -> Advanced. Fully qualified domain name should be what you're looking for ...
We have the monster of a all custom built asp intranet and it sometiems send emails to people using CDONTS. The whole thing runs IIS5.0 for web and SMTP and is fed from a seperate SQL 2k server.
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