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Reaction of Carboxylic Acids with PCl₅ and SOCl₂ Carboxylic acids are converted into acid chlorides (acyl chlorides) by reaction with chlorinating agents such as phosphorus pentachloride (PCl₅) and thionyl chloride (SOCl₂). Acid chlorides are highly reactive derivatives of carboxylic acids and are widely used in organic synthesis. 1. Reaction with Phosphorus Pentachloride (PCl₅) When a carboxylic acid reacts with PCl₅, the –OH group of the carboxyl group is replaced by chlorine. General reaction
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